ASTM D4794 - 94(2009)

    Standard Test Method for Determination of Ethoxyl or Hydroxyethoxyl Substitution in Cellulose Ether Products by Gas Chromatography

    Active Standard ASTM D4794 | Developed by Subcommittee: D01.36

    Book of Standards Volume: 06.03


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    Abstract

    This test method is applicable to the determination of ethoxyl or hydroxyethoxyl substitution in cellulose ether products by a Zeisel gas chromatographic technique. The equipment and materials to be used shall include reagents, gas chromatograph, electronic integrator, column, syringe, reaction vials, caps, heating block, and a cover. The following reagents are as follows: iodoethane, O-xylene, toluene, hydrochloric acid, and colume packing. When a cellulose ether containing ethyl or hydroxyethyl substitutes is allowed to react with hydriodic acid, one mole of iodoethane is liberated for each mole of ethoxyl or hydroxyethoxyl ether substituted on the cellulose chain. The iodoethane is extracted in-situ with o-xylene and quantitated by gas chromatography using an internal standard technique. It is recommended to run duplicate samples.

    This abstract is a brief summary of the referenced standard. It is informational only and not an official part of the standard; the full text of the standard itself must be referred to for its use and application. ASTM does not give any warranty express or implied or make any representation that the contents of this abstract are accurate, complete or up to date.

    Significance and Use

    1. Scope

    1.1 This test method is applicable to the determination of ethoxyl or hydroxyethoxyl substitution in cellulose ether products by a Zeisel gas chromatographic technique.

    1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 5 and Note 3.


    ICS Code

    ICS Number Code 71.080.60 (Alcohols. Ethers)

    UNSPSC Code

    UNSPSC Code 12352200(Biochemicals)


    DOI: 10.1520/D4794-94R09

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