Significance and Use
The analysis of many types of water for metals using flame atomic absorption spectrophotometry, inductively coupled plasma emission spectrophotometry, direct current plasma emission spectrophotometry, or graphite furnace atomic absorption spectrophotometry necessitates the use of a digestion practice in order to ensure the proper statistical recovery of the metals from the sample matrix. The use of closed vessel microwave techniques will speed the complete recovery of metals from the water matrices and eliminate sample contamination from external sources.
1.1 This practice covers the general considerations for quantitative sample digestion for total metals in water using closed vessel microwave heating technique. This practice is applicable to surface, saline, domestic, and industrial wastewater.
1.2 Because of the differences among various makes and models of satisfactory instruments, no detailed operating instructions can be provided. Instead, the analyst should follow the instructions provided by the manufacturer of the particular instrument.
1.3 This practice can be used with the following ASTM standards, providing the user determines precision and bias based on this digestion practice: Test Methods D857, Test Methods D858, Test Methods D1068, Test Method D1976, Test Methods D1687, Test Methods D1688, Test Methods D1691, Test Methods D1886, Practices D3370, Test Methods D3557, Test Methods D3559, Practice D3919, Test Methods D4190, Practice D4453, Practice D4691, and Test Method D5673.
1.4 The values stated in either SI or inch-pound units are to be regarded as the standard. The values given in parentheses are for information only.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 9.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D857 Test Method for Aluminum in Water
D858 Test Methods for Manganese in Water
D1068 Test Methods for Iron in Water
D1129 Terminology Relating to Water
D1192 Guide for Equipment for Sampling Water and Steam in Closed Conduits
D1193 Specification for Reagent Water
D1687 Test Methods for Chromium in Water
D1688 Test Methods for Copper in Water
D1691 Test Methods for Zinc in Water
D1886 Test Methods for Nickel in Water
D3370 Practices for Sampling Water from Closed Conduits
D3557 Test Methods for Cadmium in Water
D3559 Test Methods for Lead in Water
D3856 Guide for Management Systems in Laboratories Engaged in Analysis of Water
D3919 Practice for Measuring Trace Elements in Water by Graphite Furnace Atomic Absorption Spectrophotometry
D4190 Test Method for Elements in Water by Direct-Current Plasma Atomic Emission Spectroscopy
D4453 Practice for Handling of High Purity Water Samples
D4691 Practice for Measuring Elements in Water by Flame Atomic Absorption Spectrophotometry
U.S. Code of Federal Regulations
CFR1.030.10 Code of Federal Regulations, Volume 21
Federal Communications Commission Standard
CodeofFederalRegulat Volume 47, FCC Rule Part 18
U.S. EPA Method
U.S.EPAMethod:SW846M Microwave Assisted Acid Digestion of Aqueous Samples and Extracts
digestion; metals; microwave; vessel; Manganese content--water; Metal content--water; Microwave ovens/procedures; Nickel content--water; Quantitative analysis/measurement--water; Selenium content--water; Silver content--water; Total recoverable elements (in water); Zinc; Aluminum; Antimony content--water; Arsenic content--water; Barium content--water; Cadmium content--water; Chromium content--water; Closed vessel microwave heating technique; Copper content--water; Digestion; Inorganic compounds--water; Iron content--water; Lead screening testing
ICS Number Code 13.060.50 (Examination of water for chemical substances)
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Citing ASTM Standards
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