ASTM D4192 - 08

    Standard Test Method for Potassium in Water by Atomic Absorption Spectrophotometry

    Active Standard ASTM D4192 | Developed by Subcommittee: D19.05

    Book of Standards Volume: 11.01


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    Significance and Use

    Potassium occurs in rocks in a form that is not easily solubilized; therefore, the potassium content of natural waters is usually low. Most natural waters contain less than 20 mg/L of potassium, but waters containing several hundred milligrams per litre are occasionally found. Potassium is essential to animal nutrition, but a concentration of 1000 to 2000 mg/L in stock water is regarded as the extreme limit permissible.

    1. Scope

    1.1 This test method covers the determination of low amounts of potassium in waters having low solids content. The applicable range of this test method is 0.20 to 4.0 mg/L when using the 766.5-nm resonance line. The range may be extended upward by dilution of an appropriate aliquot of sample or by using the less-sensitive 404.4-nm resonance line. Many workers have found that this test method is reliable for potassium levels to 0.02 mg/L, but use of this test method at this low level is dependent on the configuration of the aspirator and nebulizer systems available in the atomic absorption spectrophotometer as well as the skill of the analyst. The precision and bias data presented are insufficient to justify use of this test method in the 0.02-mg/L range.

    1.2 This test method has been used successfully with spiked reagent water. It is the analyst's responsibility to ensure the validity of this test method to other low dissolved solids matrices.

    1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

    1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific precautionary statement, see Note 3.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D1066 Practice for Sampling Steam

    D1129 Terminology Relating to Water

    D1193 Specification for Reagent Water

    D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

    D3370 Practices for Sampling Water from Closed Conduits

    D5810 Guide for Spiking into Aqueous Samples

    D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis


    ICS Code

    ICS Number Code 13.060.50 (Examination of water for chemical substances)

    UNSPSC Code

    UNSPSC Code


    Referencing This Standard

    DOI: 10.1520/D4192-08

    ASTM International is a member of CrossRef.

    Citation Format

    ASTM D4192-08, Standard Test Method for Potassium in Water by Atomic Absorption Spectrophotometry, ASTM International, West Conshohocken, PA, 2008, www.astm.org

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