Standards

ASTM D4190 - 08


ASTM D4190 - 08 Standard Test Method for Elements in Water by Direct-Current Argon Plasma Atomic Emission Spectroscopy


Active Standard ASTM D4190 Developed by Subcommittee: D19.05 |Book of Standards Volume: 11.01

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ASTM D4190

Significance and Use

This test method is useful for the determination of element concentrations in many natural waters. It has the capability for the simultaneous determination of up to 15 separate elements. High analysis sensitivity can be achieved for some elements, such as boron and vanadium.

1. Scope

1.1 This test method covers the determination of dissolved and total recoverable elements in water, which includes drinking water, lake water, river water, sea water, snow, and Type II reagent water by direct current plasma atomic emission spectroscopy (DCP).

1.2 The information on precision and bias may not apply to other waters.

1.3 This test method is applicable to the 15 elements listed in Annex A1 (Table A1.1) and covers the ranges in Table 1.

1.4 This test method is not applicable to brines unless the sample matrix can be matched or the sample can be diluted by a factor of 200 up to 500 and still maintain the analyte concentration above the detection limit.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

TABLE 1 Solutions for Analysis

Element PSolutions for Analysis, μg/L
1 2 3
Al 50 100 190
Be 50 5001000
B 50 5001000
Cd1000 50 500
Cr 5001000 50
Co 50 5001000
Cu1000 50 500
Fe 5001000 50
Pb 500 2001000
Mn 800 50 300
Hg 5001000 200
Ni 50 300 800
Sr 600 50 300
V 1000 50 400
Zn 5001000 50


2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

D1066 Practice for Sampling Steam

D1129 Terminology Relating to Water

D1193 Specification for Reagent Water

D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water

D3370 Practices for Sampling Water from Closed Conduits

D4841 Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents

D5810 Guide for Spiking into Aqueous Samples

D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis

E1097 Guide for Direct Current Plasma-Atomic Emission Spectrometry Analysis



Keywords

direct-current plasma; DCP; elements; water; Argon plasma spectrometry/spectroscopy; D-C plasma spectrometers; Dissolved elements (of water); Drinking water; Fresh water; High-purity water; Inorganic compounds--water; Reagent water; Seawater (natural/synthetic); Total recoverable elements (in water);



ICS Code

ICS Number Code 13.060.50 (Examination of water for chemical substances)



DOI: 10.1520/D4190-08

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