ASTM D3703 - 13

    Standard Test Method for Hydroperoxide Number of Aviation Turbine Fuels, Gasoline and Diesel Fuels

    Active Standard ASTM D3703 | Developed by Subcommittee: D02.05

    Book of Standards Volume: 05.01

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    Significance and Use

    5.1 The magnitude of the hydroperoxide number is an indication of the quantity of oxidizing constituents present. Deterioration of the fuels results in the formation of hydroperoxides and other oxygen-carrying compounds. The hydroperoxide number measures those compounds that will oxidize potassium iodide.

    5.2 The determination of the hydroperoxide number of aviation turbine fuels, gasoline and diesel is significant because of the adverse effect of hydroperoxide upon certain elastomers in the fuel systems.

    5.3 The determination of hydroperoxide number of gasoline is significant because hydroperoxides have been demonstrated to decrease both Research and Motor Octane Numbers. In addition, hydroperoxides have adverse effects on certain fuel system components.

    5.4 The determination of hydroperoxide number of diesel fuel is significant because hydroperoxides have been demonstrated to increase the Cetane Number. In addition, hydroperoxides have adverse effects on certain fuel system components.

    1. Scope

    1.1 This test method covers the determination of the hydroperoxide content expressed as hydroperoxide number of aviation turbine, gasoline and diesel fuels.

    1.2 The range of hydroperoxide number included in the precision statement is 0 to 50 mg/kg active oxygen as hydroperoxide.

    1.3 The interlaboratory study to establish the precision of this test method consisted of spark-ignition engine fuels (regular, premium and California Cleaner-Burning gasoline), aviation gasoline, jet fuel, ultra low sulfur diesel, and biodiesel. However, biodiesel was not included in the precision calculation because of the large differences in results within labs and between labs.

    1.4 This test method detects hydroperoxides such as t-butyl hydroperoxide and cumene hydroperoxide. It does not detect sterically-hindered hydroperoxides such as dicumyl and di-t-butyl hydroperoxides

    1.5 Di-alkyl hydroperoxides added commercially to diesel fuels are not detected by this test method.

    1.6 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

    1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to consult and establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see 7.3, 7.6, 9.2, and Annex A1.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D1193 Specification for Reagent Water

    D4057 Practice for Manual Sampling of Petroleum and Petroleum Products

    D6447 Test Method for Hydroperoxide Number of Aviation Turbine Fuels by Voltammetric Analysis

    Other Standards

    4500-C1B. Iodometric Method I--Standard Methods for the Examination of Water and Wastewater Published by the American Health Assoc., the American Water Works Assoc. and Water Environment Federation. Available from American Public Health Publication Sales, P. O. Box 753, Waldorf, MD 20604-0753.

    CRCReportNo.559 Determination of the Hydroperoxide Potential of Jet Fuels Available from the Coordinating Research Council, Inc., 219 Perimeter Center Parkway, Atlanta, GA 30346.

    ICS Code

    ICS Number Code 75.160.20 (Liquid fuels)

    UNSPSC Code

    UNSPSC Code 15101500(Petroleum and distillates)

    DOI: 10.1520/D3703

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