Significance and Use
4.1 The test for cadmium is necessary because it is a toxicant and because there is a limit specified for cadmium in potable water in the National Interim Primary Drinking Water Regulations. This test serves to determine whether the cadmium content of potable water is above or below the acceptable limit.
1. Scope
1.1 These test methods cover the determination of dissolved and total recoverable cadmium in water and wastewater by atomic-absorption spectrophotometry and differential pulse anodic stripping voltammetry. Four test methods are included as follows:
| | Concentration Range | Sections |
| Test Method A—Atomic Absorption, Direct | 0.05 to 2.0 mg/L | 7 to 15 |
| Test Method B—Atomic Absorption, Chelation-Extraction | 5 to 200 μg/L | 16 to 24 |
| Test Method C—Differential Pulse Anodic Stripping Voltammetry | 1 to 100 μg/L | 25 to 34 |
| Test Method D—Atomic Absorption, Graphite Furnace | 2 to 10 μg/L | 35 to 43 |
1.2 Test Method B can be used to determine cadmium in brines. It is the user's responsibility to ensure the validity of these test methods for waters of untested matrices.
1.3 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system are mathematical conversions and may not be exact equivalents; therefore, each system shall be used independently of the other.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately)
The documents listed below are referenced within the subject standard but are not provided as part of the standard.
ASTM Standards
D858 Test Methods for Manganese in Water
D1066 Practice for Sampling Steam
D1068 Test Methods for Iron in Water
D1129 Terminology Relating to Water
D1193 Specification for Reagent Water
D1687 Test Methods for Chromium in Water
D1688 Test Methods for Copper in Water
D1691 Test Methods for Zinc in Water
D1886 Test Methods for Nickel in Water
D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
D3370 Practices for Sampling Water from Closed Conduits
D3558 Test Methods for Cobalt in Water
D3559 Test Methods for Lead in Water
D3919 Practice for Measuring Trace Elements in Water by Graphite Furnace Atomic Absorption Spectrophotometry
D4841 Practice for Estimation of Holding Time for Water Samples Containing Organic and Inorganic Constituents
D5810 Guide for Spiking into Aqueous Samples
D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
Keywords
atomic absorption; cadmium; chelation; differential pulse anodic stripping; flame; graphite furnace; voltammetry; water;
ICS Code
ICS Number Code 13.060.50 (Examination of water for chemical substances)
DOI: 10.1520/D3557-12
ASTM International is a member of CrossRef.
Citing ASTM Standards
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