Significance and Use
Cyanide is highly toxic. Regulations have been established to require the monitoring of cyanide in industrial and domestic wastes and in surface waters (Appendix X1).
Test Method D is applicable for natural water and clean metal finishing or heat treatment effluents. It may be used for process control in wastewater treatment facilities providing its applicability has been validated by Test Method B or C.
The spot test outlined in Annex A1 can be used to detect cyanide and thiocyanate in water or wastewater, and to approximate its concentration.
1.1 These test methods cover the determination of cyanides in water. The following test methods are included:
|Test Method A—Total Cyanides after Distillation||12 to 18|
|Test Method B—Cyanides Amenable to Chlorination by Difference||19 to 25|
|Test Method C—Weak Acid Dissociable Cyanides||26 to 32|
|Test Method D—Cyanides Amenable to Chlorination without Distillation (Short-Cut Method)||33 to 39|
1.2 Cyanogen halides may be determined separately.
Note 1—Cyanogen chloride is the most common of the cyanogen halide complexes as it is a reaction product and is usually present when chlorinating cyanide-containing industrial waste water. For the presence or absence of CNCl, the spot test method given in Annex A1 can be used.
1.3 These test methods do not distinguish between cyanide ions and metallocyanide compounds and complexes. Furthermore, they do not detect the cyanates. Cyanates can be determined using ion chromatography without digestion.
Note 2—The cyanate complexes are decomposed when the sample is acidified in the distillation procedure.
1.4 The cyanide in cyanocomplexes of gold, platinum, cobalt and some other transition metals is not completely recovered by these test methods. Refer to Test Method D6994 for the determination of cyanometal complexes.
1.5 Cyanide from only a few organic cyanides are recovered, and those only to a minor extent.
1.6 Part or all of these test methods have been used successfully with reagent water and various waste waters. It is the user's responsibility to assure the validity of the test method for the water matrix being tested.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in sections 5.1, 8.8, 8.18, 9, 11.3, and 16.1.9.
12.1 This test method covers the determination of cyanides in water, including the iron cyanide complexes (total cyanide).
12.2 The cyanide in some cyano complexes of transition metals, for example, cobalt, gold, platinum, etc., is not determined.
12.3 The cyanide concentration can be determined with titration, IC-PAD, colorimetric, selective ion electrode procedure, or flow injection analysis with gas diffusion separation and amperometric detection as described in Test Method D6888.
12.4 This test method has been used successfully on reagent and surface water and coke plant, refinery, and sanitary waste waters. It is the user's responsibility to assure the validity of the test method for the water matrix being tested.
12.5 Because of the sample preservation, certain suspended and/or colloidal forms of metal cyanide complexes such as those from iron and copper will dissolve prior to the distillation step. The recovery of this cyanide may depend on solution parameters such as the cyanide concentration in suspended solids, ionic strength of the sample, sample temperature, acid digestion times, and so forth.
19.1 This test method covers the determination of cyanides amenable to chlorination in water.
19.2 Iron cyanides are the most commonly encountered compounds not amenable to chlorination.
19.3 This test method has been used on reagent, surface, and industrial waste waters. It is the user's responsibility to assure the validity of the test method for the water matrix being tested.
26.1 This test method covers the determination of cyanide compounds and weak acid dissociable complexes in water.
26.2 The thiocyanate content of a sample usually does not cause interference.
26.3 Any of the three procedures, titration, colorimetric, or selective ion electrode, can be used to determine the cyanide content of the absorption solution. The lower limits of detectability are the same as for Test Method A.
26.4 This test method has been used successfully on reagent and surface water and coke plant, refinery and sanitary waste waters. It is the user's responsibility to assure the validity of the test method for the water matrix being tested.
33.1 This test method covers the determination of free CN− and CN− complexes that are amenable to chlorination in water. The procedure does not measure cyanates nor iron cyanide complexes. It does, however, determine cyanogen chloride and thiocyanate.
33.2 Modification is outlined for its use in the presence of thiocyanate.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D1129 Terminology Relating to Water
D1193 Specification for Reagent Water
D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
D3370 Practices for Sampling Water from Closed Conduits
D5788 Guide for Spiking Organics into Aqueous Samples
D5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
D6696 Guide for Understanding Cyanide Species
D6888 Test Method for Available Cyanide with Ligand Displacement and Flow Injection Analysis (FIA) Utilizing Gas Diffusion Separation and Amperometric Detection
D6994 Test Method for Determination of Metal Cyanide Complexes in Wastewater, Surface Water, Groundwater and Drinking Water Using Anion Exchange Chromatography with UV Detection
D7284 Test Method for Total Cyanide in Water by Micro Distillation followed by Flow Injection Analysis with Gas Diffusion Separation and Amperometric Detection
D7365 Practice for Sampling, Preservation and Mitigating Interferences in Water Samples for Analysis of Cyanide
D7511 Test Method for Total Cyanide by Segmented Flow Injection Analysis, In-Line Ultraviolet Digestion and Amperometric Detection
E60 Practice for Analysis of Metals, Ores, and Related Materials by Spectrophotometry
E275 Practice for Describing and Measuring Performance of Ultraviolet and Visible Spectrophotometers
colorimetric; cyanides amendable to chlorination; distillation; ion chromatography; ion electrode; titration; total cyanide; weak acid dissociable cyanides; Cyanides; Organic compounds--water ;
ICS Number Code 13.060.50 (Examination of water for chemical substances)
ASTM International is a member of CrossRef.
Citing ASTM Standards
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