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Significance and Use
The measurement of mercaptans in natural gas is important, because mercaptans are often added as odorants to natural gas to provide a warning property. The odor provided by the mercaptan serves to warn consumers (for example, residential use) of natural gas leaks at levels that are well below the flammable or suffocating concentration levels of natural gas in air. Field determinations of mercaptans in natural gas are important because of the tendency of the mercaptan concentration to fade over time.
This test method provides inexpensive field screening of mercaptans. The system design is such that it may be used by nontechnical personnel, with a minimum of proper training.
1.1 This test method covers a rapid and simple field determination of mercaptans in natural gas pipelines. Available detector tubes provide a total measuring range of 0.5 to 160 ppm by volume of mercaptans, although the majority of applications will be on the lower end of this range (that is, under 20 ppm). Besides total mercaptans, detector tubes are also available for methyl mercaptan (0.5 to 100 ppm), ethyl mercaptan (0.5 to 120 ppm), and butyl mercaptan (0.5 to 30 mg/M3 or 0.1 to 8 ppm).
1.2 Detector tubes are usually subject to interferences from gases and vapors other than the target substance. Such interferences may vary among brands because of the use of different detection principles. Many detector tubes will have a precleanse layer designed to remove interferences up to some maximum level. Consult manufacturer's instructions for specific interference information. Hydrogen sulfide and other mercaptans are usually interferences on mercaptan detector tubes. See Section 5 for interferences of various methods of detection.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see 7.3.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
Gas Processors Association StandardGPAStandard2188 Tentative Method for the Determination of Ethyl Mercaptan in LP Gas Using Length-of-Stain Detector Tubes, Appendix B, Test for Ethyl Mercaptan Odourant in Propane, Field Method, 1988 Available from Gas Processors Association, 6526 E. 60th St., Tulsa, OK 74145.
ICS Number Code 75.060 (Natural gas)
UNSPSC Code 15111500(Gaseous fuels)
ASTM D1988-06(2011), Standard Test Method for Mercaptans in Natural Gas Using Length-of-Stain Detector Tubes , ASTM International, West Conshohocken, PA, 2011, www.astm.orgBack to Top