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Significance and Use
5.1 Refractive index is a fundamental physical property that can be used in conjunction with other properties to characterize pure hydrocarbons and their mixtures.
5.2 The use of refractive index in correlative methods for the determination of the gross composition of viscous oils and waxes often requires its measurement at elevated temperatures.
1.1 This test method covers the measurement of refractive indexes, accurate to two units in the fourth decimal place, of transparent and light-colored viscous hydrocarbon liquids and melted solids that have refractive indexes in the range between 1.33 and 1.60, and at temperatures from 80 to 100°C. Temperatures lower than 80°C can be used provided that the melting point of the sample is at least 10°C below the test temperature.
1.2 This test method is not applicable, within the accuracy stated, to liquids having colors darker than ASTM Color No. 4, ASTM color as determined by Test Method , to liquids which smoke or vaporize readily at the test temperature, or to solids melting within 10°C of the test temperature.
Note 1: The instrument can be successfully used for refractive indices above 1.60; but since certified liquid standards for ranges above 1.60 are not yet available, the accuracy of measurement under these conditions has not been evaluated.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 Warning—Mercury has been designated by EPA and many state agencies as a hazardous material that can cause central nervous system, kidney, and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury-containing products. See the applicable product Material Safety Data Sheet (MSDS) for details and EPA’s website (http://www.epa.gov/mercury/faq.htm) for additional information. Users should be aware that selling mercury or mercury-containing products, or both, in your state may be prohibited by state law.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
D362 Specification for Industrial Grade Toluene
D841 Specification for Nitration Grade Toluene
D1500 Test Method for ASTM Color of Petroleum Products (ASTM Color Scale)
D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
E1 Specification for ASTM Liquid-in-Glass Thermometers
E77 Test Method for Inspection and Verification of Thermometers
ICS Number Code 17.180.30 (Optical measuring instruments); 75.080 (Petroleum products in general)