ASTM D1319 - 15

    Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption

    Active Standard ASTM D1319 | Developed by Subcommittee: D02.04.0C

    Book of Standards Volume: 05.01

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    Significance and Use

    5.1 The determination of the total volume percent of saturates, olefins, and aromatics in petroleum fractions is important in characterizing the quality of petroleum fractions as gasoline blending components and as feeds to catalytic reforming processes. This information is also important in characterizing petroleum fractions and products from catalytic reforming and from thermal and catalytic cracking as blending components for motor and aviation fuels. This information is also important as a measure of the quality of fuels, such as specified in Specification D1655.

    1. Scope

    1.1 This test method covers the determination of hydrocarbon types over the concentration ranges from 5 to 99 volume % aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume % saturates in petroleum fractions that distill below 315 °C. This test method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.

    Note 1: For the determination of olefins below 0.3 volume %, other test methods are available, such as Test Method D2710.

    1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision statement does not apply to narrow boiling petroleum fractions near the 315 °C limit. Such samples are not eluted properly, and results are erratic.

    1.3 This test method includes a relative bias section based on Practice D6708 accuracy assessment between Test Method D1319 and Test Method D5769 for total aromatics in spark-ignition engine fuels as a possible Test Method D1319 alternative to Test Method D5769 for U.S. EPA spark-ignition engine fuel regulations reporting. The Practice D6708 derived correlation equation is only applicable for fuels in the total aromatic concentration range from 3.3 % to 34.4 % by volume as measured by Test Method D1319 and the distillation temperature T95, at which 95 % of the sample has evaporated, ranges from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F) when tested according to Test Method D86.

    1.3.1 The applicable Test Method D5769 range for total aromatics is 3.7 % to 29.4 % by volume as reported by Test Method D5769 and the distillation temperature T95 values, at which 95 % of the sample has evaporated, when tested according to Test Method D86 is from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F).

    1.4 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar sands, has not been determined, and the precision statement may or may not apply to such products.

    1.5 This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures. The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with a concentration range of 13 to 40 volume percent aromatics, 4 to 33 volume percent olefins, and 45 to 68 volume percent saturates.

    1.6 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME), and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed, correct the results to a total-sample basis.

    1.7 WARNING—Mercury has been designated by many regulatory agencies as a hazardous material that can cause central nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution should be taken when handling mercury and mercury containing products. See the applicable product Material Safety Data Sheet (MSDS) for details and EPA’s website——for additional information. Users should be aware that selling mercury and/or mercury containing products into your state or country may be prohibited by law.

    1.8 The values stated in SI units are to be regarded as standard.

    1.8.1 Exception—Inch-pound units in parentheses are provided for information only.

    1.9 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see Section 7, 8.1, and 10.5.

    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    D86 Test Method for Distillation of Petroleum Products and Liquid Fuels at Atmospheric Pressure

    D1655 Specification for Aviation Turbine Fuels

    D2710 Test Method for Bromine Index of Petroleum Hydrocarbons by Electrometric Titration

    D3663 Test Method for Surface Area of Catalysts and Catalyst Carriers

    D4057 Practice for Manual Sampling of Petroleum and Petroleum Products

    D4815 Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography

    D5599 Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection

    D5769 Test Method for Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by Gas Chromatography/Mass Spectrometry

    D6708 Practice for Statistical Assessment and Improvement of Expected Agreement Between Two Test Methods that Purport to Measure the Same Property of a Material

    E11 Specification for Woven Wire Test Sieve Cloth and Test Sieves

    ICS Code

    ICS Number Code 75.080 (Petroleum products in general)

    UNSPSC Code

    UNSPSC Code 15101500(Petroleum and distillates)

    Referencing This Standard
    Link Here
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    DOI: 10.1520/D1319-15

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    Citation Format

    ASTM D1319-15, Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption, ASTM International, West Conshohocken, PA, 2015,

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