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Significance and Use
5.1 These test methods provide data useful for evaluating the chemical durability (see 3.1.5) of glass waste forms as measured by elemental release. Accordingly, it may be applicable throughout manufacturing, research, and development.
5.1.1 Test Method A can specifically be used to obtain data to evaluate whether the chemical durability of glass waste forms have been consistently controlled during production (see Table 1).
5.1.2 Test Method B can specifically be used to measure the chemical durability of glass waste forms under various test conditions, for example, varying test durations, test temperatures, ratios of sample-surface area (S) to leachant volume (V) (see Appendix X1), and leachant types (see Table 1). Data from this test may form part of the larger body of data that are necessary in the logical approach to long-term prediction of waste form behavior (see Practice C1174).
1.1 These product consistency test methods A and B provide a measure of the chemical durability of homogeneous glasses, phase separated glasses, devitrified glasses, glass ceramics, multiphase glass ceramic waste forms, or combinations thereof, hereafter collectively referred to as “glass waste forms” by measuring the concentrations of the chemical species released to a test solution under carefully controlled conditions.
1.1.1 Test Method A is a seven-day chemical durability test performed at 90 ± 2°C in a leachant of ASTM-Type I water. The test method is static and conducted in stainless steel vessels. The stainless steel vessels require a gasket to remain leak-tight.2 The stainless steel vessels are considered to be “closed system” tests. Test Method A can specifically be used to evaluate whether the chemical durability and elemental release characteristics of nuclear, hazardous, and mixed glass waste forms have been consistently controlled during production. This test method is applicable to radioactive and simulated glass waste forms as defined above.
1.1.2 Test Method B is a durability test that allows testing at various test durations, test temperatures, particle size and masses of glass sample, leachant volumes, and leachant compositions. This test method is static and can be conducted in stainless steel or PFA TFE-fluorocarbon vessels. The stainless steel vessels are considered to be “closed system” while the PFA TFE-fluorocarbon vessels are considered to be “open system” tests. Test Method B can specifically be used to evaluate the relative chemical durability characteristics of homogeneous glasses, phase separated glasses, devitrified glasses, glass ceramics, or multiphase glass ceramic waste forms, or combinations thereof. This test method is applicable to radioactive (nuclear) and mixed, hazardous, and simulated glass waste forms as defined above. Test Method B cannot be used as a consistency test for production of high level radioactive glass waste forms.
1.2 These test methods must be performed in accordance with all quality assurance requirements for acceptance of the data.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
C92 Test Methods for Sieve Analysis and Water Content of Refractory Materials
C162 Terminology of Glass and Glass Products
C169 Test Methods for Chemical Analysis of Soda-Lime and Borosilicate Glass
C225 Test Methods for Resistance of Glass Containers to Chemical Attack
C371 Test Method for Wire-Cloth Sieve Analysis of Nonplastic Ceramic Powders
C429 Test Method for Sieve Analysis of Raw Materials for Glass Manufacture
C693 Test Method for Density of Glass by Buoyancy
C859 Terminology Relating to Nuclear Materials
C1109 Practice for Analysis of Aqueous Leachates from Nuclear Waste Materials Using Inductively Coupled Plasma-Atomic Emission Spectroscopy
C1174 Practice for Prediction of the Long-Term Behavior of Materials, Including Waste Forms, Used in Engineered Barrier Systems (EBS) for Geological Disposal of High-Level Radioactive Waste
C1220 Test Method for Static Leaching of Monolithic Waste Forms for Disposal of Radioactive Waste
C1463 Practices for Dissolving Glass Containing Radioactive and Mixed Waste for Chemical and Radiochemical Analysis
C1662 Practice for Measurement of the Glass Dissolution Rate Using the Single-Pass Flow-Through Test Method
D859 Test Method for Silica in Water
D1129 Terminology Relating to Water
D1193 Specification for Reagent Water
D1293 Test Methods for pH of Water
D4327 Test Method for Anions in Water by Suppressed Ion Chromatography
D5956 Guide for Sampling Strategies for Heterogeneous Wastes
E7 Terminology Relating to Metallography
E177 Practice for Use of the Terms Precision and Bias in ASTM Test Methods
E456 Terminology Relating to Quality and Statistics
E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
E1402 Guide for Sampling Design
ICS Number Code 13.030.30 (Special wastes)
UNSPSC Code 11141608(Hazardous waste or scrap)