ASTM B809 - 95(2013)

    Standard Test Method for Porosity in Metallic Coatings by Humid Sulfur Vapor (“Flowers-of-Sulfur”)

    Active Standard ASTM B809 | Developed by Subcommittee: B08.10

    Book of Standards Volume: 02.05


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    Significance and Use

    5.1 A major use of this test procedure is for determining coating quality. Porosity tests are indications of the completeness of protection or coverage offered by the coatings, since the coatings described in 1.2 are intended to be protective when properly applied. The porosity test results are therefore a measure of the deposition process control.

    5.2 A particular purpose of the humid sulfur vapor test is for determining the quality of underplates of nickel or nickel alloy in those finish systems that have thin, 1.2 μm or less (50 μin. or less) top layers above the nickel, since porosity in the underplate usually continues into such top layers.

    5.3 The humid sulfur vapor test is often used as an environmental test to simulate many indoor humid atmosphere tarnishing and tarnish creepage effects. However, the chemistry and properties of these tarnish films may not resemble those found in other service environments. For such product performance evaluations, the test should only be used in combination with other performance evaluation tests, as specified in the referencing document for that product.

    5.4 Porosity tests differ from corrosion and aging tests, since the latter are intended to measure the chemical inertness of the coating. In contrast, in a good porosity test procedure the corrosive agent should not attack the coating. It must instead, clean, depolarize, or activate the substrate metal exposed by the pore, or both, and attack it sufficiently to cause reaction products to fill the pore to the surface of the coating.

    5.5 The humid sulfur test is highly sensitive, and is capable of detecting virtually all porosity that penetrates down to copper or copper alloys. Since nickel is not attacked by moist sulfur vapor at 100°C or less, this test will not detect pores or cracks in the top coating if such pores or cracks do not penetrate through the nickel underplate overlaying the copper.

    5.6 The level of porosity in the coating that may be tolerable depends on the severity of the environment that the product is likely to encounter during service or storage. Also, the location of the pores on the surface is important. If the pores are few in number or away from the significant surfaces, their presence can often be tolerated.

    5.7 The present test method can be used on samples of various geometries, such as curved surfaces. It can also be used for selective area coatings, if allowance is made for tarnish creepage from bare copper alloy areas.

    5.8 This test method is destructive in that it reveals the presence of porosity by contaminating the surface with tarnish films. Any parts exposed to this test method should not be placed in service.

    5.9 The relationship of porosity levels revealed by this test method to product performance and service life must be made by the user of the test through practical experience or by judgment. Thus, absence of porosity in the coating may be a requirement for some applications, while a few pores on the significant surfaces may be acceptable for others.

    1. Scope

    1.1 This standard covers equipment and test methods for determining the porosity of metallic coatings, where the pores penetrate down to a silver, copper, or copper-alloy substrate.

    1.2 This test method is suitable for coatings consisting of single or combined layers of any coating that does not significantly tarnish in a reduced sulfur atmosphere, such as gold, nickel, tin, tin-lead, and palladium, or their alloys.

    1.3 This test method is designed to determine whether the porosity level is less than or greater than some value which by experience is considered by the user to be acceptable for the intended application.

    1.4 Recent reviews of porosity testing and testing methods can be found in the literature.2,3 Guide B765 is suitable to assist in the selection of porosity tests for electrodeposits and related metallic coatings. Other porosity test standards are Test Methods B735, B741, B798, and B799.

    1.5 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

    1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazards statements, see Section 8.


    2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

    ASTM Standards

    B374 Terminology Relating to Electroplating

    B542 Terminology Relating to Electrical Contacts and Their Use

    B735 Test Method for Porosity in Gold Coatings on Metal Substrates by Nitric Acid Vapor

    B741 Test Method for Porosity In Gold Coatings On Metal Substrates By Paper Electrography

    B765 Guide for Selection of Porosity and Gross Defect Tests for Electrodeposits and Related Metallic Coatings

    B798 Test Method for Porosity in Gold or Palladium Coatings on Metal Substrates by Gel-Bulk Electrography

    B799 Test Method for Porosity in Gold and Palladium Coatings by Sulfurous Acid/Sulfur-Dioxide Vapor


    ICS Code

    ICS Number Code 25.220.40 (Metallic coatings)

    UNSPSC Code

    UNSPSC Code


    Referencing This Standard

    DOI: 10.1520/B0809

    ASTM International is a member of CrossRef.

    Citation Format

    ASTM B809-95(2013), Standard Test Method for Porosity in Metallic Coatings by Humid Sulfur Vapor (“Flowers-of-Sulfur”), ASTM International, West Conshohocken, PA, 2013, www.astm.org

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