SEDL / STP / STP1277-EB / STP37973S



Electrochemical Noise Measurements During Exfoliation of Aluminum Alloys

de Damborenea, J
Senior Research, Centro Nacional de Investigaciones Metalúrgicas (CENIM-CSIC), Avenida de Gregorio del Amo, Madrid,

Fernández, B
Senior Research, Centro Nacional de Investigaciones Metalúrgicas (CENIM-CSIC), Avenida de Gregorio del Amo, Madrid,


Pages: 13    Published: Jan 1996


Download this paper for $25 PDF (252K)          View License Agreement
        Click here to download the complete source publication for $123 PDF (9.7M)


Source: STP1277-EB


Abstract

Electrochemical noise measurements (ENMs) have been carried out during exfoliation corrosion of an aluminum-lithium alloy (8090) in the EXCO (ASTM Test Method for Exfoliation Corrosion Susceptibility in 2XXX and 7XXX Series Aluminum Alloys [EXCO Test] [G 34]) test solution. By means of the maximum entropy method (MEM), the potential and current fluctuations were converted into power spectral density (PSD) plots to study the specific variables related to electrochemical noise (low frequency amplitude, slopes). Noise resistance obtained from the standard deviation of potential and current was compared with the charge transference resistance (Rct) from electrochemical impedance spectroscopy (EIS) measurements. The results show that ENM can be used to detect early stages in localized corrosion. However, when the solution is very aggressive, indications of localized corrosion can be masked by uniform corrosion.


Keywords:
electrochemical noise measurement, intergranular corrosion, exfoliation corrosion, EXCO test, aluminum-lithium alloy, electrochemical impedance spectroscopy

Paper ID: STP37973S
Committee/Subcommittee: G01.11
DOI: 10.1520/STP37973S
CrossRef ASTM International is a member of CrossRef.