SYMPOSIA PAPER Published: 01 January 1981
STP28099S

Spectrochemical Determination of Impurities in Uranium Following Solvent Extraction Using Tributyl Phosphate in Methyl Isobutyl Ketone

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Solvent extraction using tributyl phosphate in methyl isobutyl ketone is employed to separate the uranium matrix from the trace impurities originally present in uranium. The impurities are separated quantitatively into the acidic aqueous phase, which may then be analyzed by conventional spectroscopic techniques, including flame and flameless atomic absorption. An effective concentration of impurity levels over those present in the original sample may also be obtained by incorporating the aqueous phase into a gallium nitrate solution, which is converted to a gallium oxide matrix containing the impurities, which are then analyzed by emission spectroscopy. The method provides reasonable precision and accuracy, plus increased sensitivity when the impurities are concentrated in the gallium oxide matrix.

Author Information

Chang, JG
International Atomic Energy Agency, Vienna, Ill., Austria
Graff, RL
Spectrochemistry Section, New Brunswick Laboratory, U.S. Department of Energy, Argonne, Ill.
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Details
Developed by Committee: E03
Pages: 106–112
DOI: 10.1520/STP28099S
ISBN-EB: 978-0-8031-4813-0
ISBN-13: 978-0-8031-0743-4