SYMPOSIA PAPER Published: 01 January 1988
STP26299S

Evaluation of Protective Clothing Materials Challenged by Petroleum and Synfuel Fluids

Source

The permeation characteristics of eleven petroleum, coal, and shale oil hydrocarbon liquids through eight different types of glove were measured over 24 h. Two analytical techniques, photoionization and room-temperature phosphorescence of polynuclear aromatic compounds, were used to measure breakthrough times by volatile and low-volatility constituents, respectively. Serious drawbacks to the general use of these techniques for measuring steady-state rates of permeation were noted.

The lighter, smaller molecular-size constituents permeated faster than the larger, multi-ringed aromatic constituents. For the light hydrocarbon fuels, especially gasoline, there was preferential permeation by benzene and toluene. Nitrile was severely corroded after extended exposure to hydroxybenzene-containing coal-derived liquids. A general ranking, from worst to best, of the protection afforded by the different gloves was latex ≪ neoprene < butyl rubber, polyvinyl chloride (PVC) < nitrile < Viton, Tyvek/Saranex 23, and polyvinyl alcohol (PVA). No breakthroughs within 24 h were observed with the latter three glove materials.

Author Information

Gammage, RB
Health and Safety Research Division, Oak Ridge National Laboratory, Oak Ridge, TN
Dreibelbis, WG
Pennsylvania State University, University Park, PA
Allen White, D
Health and Safety Research Division, Oak Ridge National Laboratory, Oak Ridge, TN
Vo-Dinh, T
Health and Safety Research Division, Oak Ridge National Laboratory, Oak Ridge, TN
Huguenard, JD
Jefferson County High School, Talbott, TN
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Details
Developed by Committee: F23
Pages: 326–338
DOI: 10.1520/STP26299S
ISBN-EB: 978-0-8031-5058-4
ISBN-13: 978-0-8031-1167-7