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Influence of Hydrologic Factors on Leaching of Solidified Low-Level Waste Forms at an Arid-Site Field-Scale Lysimeter Facility
Jones, TL
Research scientist and department manager, Pacific Northwest Laboratory, WA

Skaggs, RL


Pages: 23    Published: Jan 1989


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Source: STP1033-EB


Abstract

The release of contaminants from solidified low-level waste forms is being studied in a field lysimeter facility at the Hanford Site in southeastern Washington State. The lysimeter facility, constructed in 1984, consists of ten 3-m-deep by 1.8-m-diameter steel caissons surrounding a 4-m-deep central instrument caisson. Each lysimeter contains one field-scale waste form (210-L barrel), obtained from a commercial power reactor. Solidification agents being tested include masonry cement, Portland III cement, Dow polymer, and bitumen.

Most of the precipitation at the Hanford Site arrives as winter snow; this contributes to a strong seasonal pattern in water storage and drainage observed in the lysimeters. This seasonal pattern in storage corresponds to an annual range in the volumetric soil water content of 11% in late winter to 7% in the late summer and early fall. Annual changes in drainage rates cause pore water velocities to vary by nearly two orders of magnitude, from approximately 4 cm/week in early spring to less than 0.01 cm/week in early fall.

Measurable quantities of tritium and cobalt-60 are being collected in lysimeter drainage water. Approximately 30% of the original tritium inventory has been leached from the only two waste forms containing tritium. Cobalt-60 is contained in all waste form samples and is consistently being leached from five lysimeters. Total cobalt-60 collected from each of the five lysimeters varies, but in each case is less than 0.1% of the original cobalt inventory of the waste sample.


Keywords:
solidified waste, lysimeter, leaching, radionuclide, low-level waste

Paper ID: STP22892S
Committee/Subcommittee: D34.01
DOI: 10.1520/STP22892S
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