STP1344

    Uranium Isotope Measurements by Quadrupole ICP-MS for Process Monitoring of Enrichment

    Published: Jan 1998


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    Abstract

    Historically, uranium isotopic ratio measurements in the nuclear industry have been performed using Thermal Ionization Mass Spectrometry (TIMS); primarily due to the high level of precision that can be achieved. TIMS analysis, however, requires sample purification and intricate sample loading. Quadrupole (low resolution, single detector) inductively coupled plasma — mass spectrometry, Q-ICP-MS, overcomes these disadvantages and is a cost-effective alternative, i.e., in terms of initial capital, maintenance, and operating costs. This paper presents a simple, single standard approach for measuring uranium isotope content in various solid and liquid nuclear materials along with some comparison data of Q-ICP-MS and TIMS. Intensity ratios of 234U, 235U, 236U, and 238U to total U intensity are produced, providing the enrichment level or percent 235U. A detailed description of the instrument and data collection parameters is also provided. Optimal precision and accuracy are achieved through the use of a single standard which is closely matched to the enrichment and concentration of the samples. Depending upon the standard chosen, enrichments between depleted and 97% can be quantified. Standard deviations for the major uranium isotopes are typically within 0.02 absolute and at least an order of magnitude lower for the minor U isotope abundances.

    Keywords:

    ICP-MS, isotope ratio, process monitoring, quadrupole mass spectrometry


    Author Information:

    Policke, TA
    Principal Technical Specialist, BWX Technologies, Inc., Lynchburg, VA

    Bolin, RN
    Technical Specialist III, E&QAD, BWX Technologies, Inc., Lynchburg, VA

    Harris, TL
    Chemistry Laboratory Manager, E&QAD, BWX Technologies, Inc., Lynchburg, VA


    Paper ID: STP15721S

    Committee/Subcommittee: C26.09

    DOI: 10.1520/STP15721S


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