STP1468

    Rapid Determination of Suifur in Liquid Hydrocarbons for At-Line Process Applications Using Combustion/Oxidation and UV-Fluorescence Detection

    Published: Jan 2005


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    Abstract

    With the reduction in sulfur levels in gasoline and diesel products, it is necessary to have a method available which can precisely and accurately measure the very low levels of sulfur in these fuels. ASTM test method D 5453, Sulfur by Combustion and Ultraviolet Fluorescence (UVF), is a laboratory-based technology that has been widely used in the industry for such purposes for more than a decade. An on-line/at-process version of this technique is described which can complete a fast analysis in less than one minute. Thus, near real-time data can be obtained when refineries and terminals need to make rapid determinations of sulfur levels for process control and pipeline distribution decisions involving the new generation “clean” hydrocarbon fuels. Particularly discussed is the advantage gained for decision making involving detection of transport boundaries and related custody transfer issues.

    Keywords:

    rapid sulfur analysis, gasoline analysis, diesel analysis, ultra low sulfur in diesel, combustion/oxidation UV-fluorescence detection, fast on-line/at process sulfur determination


    Author Information:

    Tarkanic, S
    Houston, TX

    Crnko, J
    Houston, TX


    Paper ID: STP12000S

    Committee/Subcommittee: D02.03

    DOI: 10.1520/STP12000S


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