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On the Embrittlement of Zircaloy-4 Under RIA-Relevant Conditions
Daum RS, Majumdar S, Bates DW, Motta AT, Koss DA, Billone MC


Pages: 18    Published: Jan 2002


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Source: STP1423-EB


Abstract
The extended use of Zircaloy cladding in light water reactors degrades its mechanical properties by a combination of irradiation embrittlement, coolant-side oxidation, hydrogen pickup, and hydride formation. The hydrides are usually concentrated in the form of a dense layer or rim near the cooler outer surface of the cladding. Utilizing plane-strain ringstretch tests to approximate the loading path in a reactivity-initiated accident (RIA) transient, we examined the influence of a hydride rim on the fracture behavior of unirradiated Zircaloy-4 cladding at room temperature and 300°C. Failure is sensitive to hydride-rim thickness such that cladding tubes with a hydride-rim thickness >100 m (700 wppm total hydrogen) exhibit brittle behavior, while those with a thickness <90 m (600 wppm) remain ductile. The mechanism of failure is identified as strain-induced crack initiation within the hydride rim and failure within the uncracked ligament due to either a shear instability or damage-induced fracture. We also report some preliminary results of the uniaxial tensile behavior of low-Sn Zircaloy-4 cladding tubes in a cold-worked, stress-relieved condition in the transverse (hoop) direction at strain rates of 0.001/s and 0.2/s and temperatures of 26 to 400°C.


Keywords:
mechanical properties, ring stretch specimens, Zircaloy-4 cladding, hydrides, hydride rim, stress-state, fracture strain

Paper ID: STP11412S
Committee/Subcommittee: B10.02
DOI: 10.1520/STP11412S
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