STP1300

    Comparison of Current Reversal Chronopotentiometry (Crc) And Small Amplitude Cyclic Voltammetry (Sacv) Method To Determine The Long-Term Corrosion Tendency Of Copper-Nickel Alloys in Polluted And Unpolluted Seawater Under Jet-Impingement Conditions

    Published: Jan 1997


      Format Pages Price  
    PDF Version (252K) 16 $25   ADD TO CART
    Complete Source PDF (3.4M) 16 $55   ADD TO CART


    Abstract

    The cyclic current reversal chronopotentiometry (CRC) technique is utilized to determine the long-term corrosion tendency of UNS C70600 and UNS C71500 copper-nickel alloys in sulfide polluted and unpolluted seawater. The CRC results were compared with the corrosion tendency obtained by the modified linear polarization method Small Amplitude Cyclic Voltammetry (SACV) over a long exposure time and the results are in agreement for both C70600 and C715OO alloys. This contradicts the conclusions on the effects of sulfide on copper-nickel alloys by many previous investigators who misinterpreted the sharp active shift in potential as an indication of increase in corrosion rate. For an active/passive alloy such as C71500 a higher amplitude current per cycle is required (e.g. 100 μA/20 seconds) in the CRC method and under jet-impingement conditions, while a lower amplitude current per cycle (e.g. lμA/20 seconds) is required for an alloy that does not exhibit active/passive behavior. The CRC technique was found to be unsuccessful in screening out the long-term corrosion tendency of copper alloys in polluted and unpolluted sea water and under stagnant or stirred conditions (i. e. non-jet-impingement conditions).

    Keywords:

    Current Reversal Chronopotentiometry (CRC), sea water, jet-impingement, Small Amplitude Cyclic Voltammetry (SACV)


    Author Information:

    Reda, MR
    Corrosion and Environmental Control Consultant, Burlington, Ontario

    Alhajji, JN
    Corrosion and Materials Laboratory, College of Engineering and Petroleum, Kuwait University, Safat,


    Paper ID: STP11362S

    Committee/Subcommittee: G01.09

    DOI: 10.1520/STP11362S


    CrossRef ASTM International is a member of CrossRef.