Oxidation Fundamentals and Its Application to Turbine Oil Testing

    Volume 3, Issue 4 (April 2006)

    ISSN: 1546-962X

    CODEN: JAIOAD

    Page Count: 20


    Gatto, VJ
    Albemarle Corporation, Baton Rouge, LA

    Moehle, WE
    Albemarle Corporation, Baton Rouge, LA

    Cobb, TW
    Albemarle Corporation, Baton Rouge, LA

    Schneller, ER
    Albemarle Corporation, Baton Rouge, LA

    (Received 31 October 2005; accepted 21 February 2006)

    Abstract

    The current turbine oil oxidation bench tests have been in place for many years. Recently, however, the basestocks used to formulate these lubricants have changed significantly. Traditional basestocks, containing high levels of aromatics and sulfur, have been substantially displaced by more highly refined basestocks, which have very low levels of aromatics and almost no sulfur. Over time it has become clear that the oxidation performance of the different basestock classes is quite different. One key question, however, remains unanswered. “What modifications are required in current bench tests to adequately mimic oxidation processes in modern turbine lubricants?” In order to adequately address this critical question, the fundamentals of lubricant oxidation and stabilization will be discussed. Data will be presented on the oxidation of different basestocks under varying conditions of temperature, metal catalysts and antioxidant type, using model bulk oil oxidation tests. The data highlights the fundamental oxidation mechanisms that can occur in turbine oil systems and new test methods are proposed.


    Paper ID: JAI13498

    DOI: 10.1520/JAI13498

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    Author
    Title Oxidation Fundamentals and Its Application to Turbine Oil Testing
    Symposium Oxidation and Testing of Turbine Oils, 2005-12-08
    Committee D02