Effect of Hard Water and Ammonium Sulfate on Weak Acid Herbicide Activity

    Volume 7, Issue 6 (June 2010)

    ISSN: 1546-962X

    CODEN: JAIOAD

    Published Online: 2 July 2010

    Page Count: 10


    Zollinger, Richard K.
    Professor, Dept. of Plant Sciences, North Dakota State Univ., Fargo, ND

    Nalewaja, John D.
    Professor Emeritus, Dept. of Plant Sciences, North Dakota State Univ., Fargo, ND

    Peterson, Dallas E.
    Professor, Dept. of Agronomy, Kansas State Univ., Manhattan, KS

    Young, Bryan G.
    Professor, Dept. of Plant, Soil and Agricultural Systems, Southern Illinois Univ., Carbondale, IL

    (Received 16 November 2009; accepted 25 May 2010)

    Abstract

    Glyphosate is a weak acid herbicide and can bind with calcium in the spray carrier. Diammonium sulfate is commonly used as an adjuvant with glyphosate to enhance phytotoxicity and overcome antagonistic effect of these cations. Most postemergence herbicides are also weak acid herbicides. Data is limited for other weak acid herbicides and the effect of diammonium sulfate in enhancing herbicide activity and overcoming antagonism. Field studies were conducted with aminopyralid, tembotrione, dicamba plus diflufenzopyr, and glufosinate to determine if (1) these weak acid herbicides are enhanced by ammonium, (2) if they are antagonized by calcium and magnesium in the spray solution, (3) if diammonium sulfate overcomes salt antagonism, and (4) if a previously published equation for the amount of ammonium sulfate required to overcome salt antagonism of glyphosate based on cation concentration in spray water correctly predicts to other weak acid herbicides. The activity of the four weak acid herbicides increased with the addition of ammonium to the spray solution, all were antagonized by calcium and magnesium, and diammonium sulfate overcame the antagonism. The previously published equation to calculate the amount the diammonium sulfate needed to overcome 500 and 1000 ppm hardness was accurate and can be used for these herbicides and possibly other weak acid herbicides.


    Paper ID: JAI102869

    DOI: 10.1520/JAI102869

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    Author
    Title Effect of Hard Water and Ammonium Sulfate on Weak Acid Herbicide Activity
    Symposium Pesticide Formulations and Delivery Systems: Regulations and Innovation, 2009-10-22
    Committee E35