Volume 6, Issue 10 (November 2009)

    Ignition of Contaminated Aluminum by Impact in Liquid Oxygen—Influence of Oxygen Purity

    (Received 5 December 2008; accepted 19 August 2009)

    Published Online: 2009

    CODEN: JAIOAD

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    Abstract

    Impact tests in liquid oxygen and oxygen enriched liquids have been conducted on aluminum foils (0.2 mm thick) used for heat exchangers of air separation units (ASUs). Some adaptations to the ASTM Standard D2512, “Standard Test Method for Compatibility of Materials with Liquid Oxygen,” have been done to ensure the good control of oxygen content in the cryogenic liquid and to get reproducible results in aluminum ignition with hydrocarbon coating. Modified striker pins with a cavity on the contact surface have been used. The vertical guiding and the centering of the striker pins have been ensured by using two machined guides. Test samples were three layers of aluminum foil, two corrugated and one flat, contaminated by various quantities of hexadecane. The criteria for the identification of aluminum ignition (positive tests) have been validated by performing Scanning electron microscope surface analysis on residuals of a few impact tests performed in copper cups. Criteria have also been defined to check that hexadecane combustion took place in negative tests. A sufficient number of tests have been performed to plot the probability of ignition of the aluminum samples as a function of the average thickness of hexadecane coating and as a function of the oxygen content in the cryogenic liquid varying from 50 % to above 99.95 %. The remaining part in the cryogenic liquid was nitrogen and 2.3 % argon except for one series of tests where the influence of the absence of argon could be identified. The results of these tests can be used to assess the risk of ignition of some aluminum exchangers or structures used in ASU.


    Author Information:

    Werlen, Etienne
    Air Liquide Engineering, Champigny-sur-Marne,

    Crayssac, Frédéric
    CRCD, Air Liquide R&D, Les-Loges-en-Josas,

    Longuet, Olivier
    CTE, Air Liquide Testing Center, Le Blanc-Mesnil,

    Willot, Fabien
    CTE, Air Liquide Testing Center, Le Blanc-Mesnil,


    Stock #: JAI102264

    ISSN: 1546-962X

    DOI: 10.1520/JAI102264

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    Author
    Title Ignition of Contaminated Aluminum by Impact in Liquid Oxygen—Influence of Oxygen Purity
    Symposium Twelfth International Symposium on Flammability and Sensitivity of Materials in Oxygen-Enriched Atmospheres, 2009-10-09
    Committee G04